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Silk has a great look to it, and feels great on your feet when it's a bit warm! Can also be very cold when it's cold, and if you have sweaty feet they may stick to it and move the rug around a lot! Personally, I would suggest a wool rug! They go with just about anything, feel great and soft on the toes no matter what the weather is. But if you're looking for more of a rich, fancy look, I would say go for the silk!
A silk rug would be the best.